高砷铅阳极泥常压碱浸脱砷试验研究  

Removal of Arsenic From High Arsenic-lead Anode Slime by Alkaline Leaching at Atmospheric Pressure

作　　者：喻小强 徐家聪 易勤 温盛汇 田磊[1] YU Xiaoqiang;XU Jiacong;YI Qin;WEN Shenghui;TIAN Lei(Institute of Green Metallurgy and Process Intensification,Jiangxi University of Science and Technology,Ganzhou 341000)

机构地区：[1]江西理工大学绿色冶金与过程强化研究所,江西赣州341000

出　　处：《湿法冶金》2021年第4期342-346,共5页Hydrometallurgy of China

基　　金：国家自然科学基金资助项目(51804136,52064021,52074136);中国博士后科学基金资助项目(2019T120625,2019M652276);江西省主要学科学术与技术带头人-青年人才培养计划项目(20204BCJL23031),江西省杰出青年科学基金资助项目(20202ACB213002);江西理工大学青年英才支持计划、江西省青年井冈学者、江西省博士后科研项目择优资助项目(2019KY09)。

摘　　要：研究了常压下从铅阳极泥中碱浸脱砷,考察了浸出时间、浸出温度、NaOH质量浓度、H2O2添加量和液固体积质量比等对砷脱除及铅、锑浸出的影响。结果表明:在阳极泥质量50 g、浸出温度90℃、H2O2添加量10 mL、NaOH质量浓度60 g/L、液固体积质量比4 mL/1 g、浸出时间90 min条件下,砷浸出率为94.98%,而铅、锑基本不溶,砷脱除效果较好。The removal of arsenic by atmospheric alkaline leaching from lead anode slime was studied.The effects of leaching time,leaching temperature,NaOH concentration,H2O2 usage and ratio of liquid volume-to-solid mass on removal of arsenic were examined.The results show that under the conditions of anode slime mass of 50 g,temperature of 90℃,H2O2 usage of 10 mL,concentration of NaOH of 60 g/L,ratio of liquid volume-to-solid mass of 4 mL/1 g and raction time of 90 min,the removal of As reaches 94.98%,while Pb and Sb are not indissolvable.Arsenic is removed effectively from the anode slime.

关 键 词：铅阳极泥 碱浸 砷 脱除 

分 类 号：TF803.21[冶金工程—有色金属冶金]