Surface passivation and boundary lubrication of self-mated tetrahedral amorphous carbon asperities under extreme tribological conditions  

作　　者：Pedro A.ROMERO Lars PASTEWKA Julian VON LAUTZ Michael MOSELER 

机构地区：[1]Fraunhofer Institute for Mechanics of Materials IWM,Wöhlerstraße 11,79108 Freiburg,Germany [2]Karlsruhe Institute of Technology,IAM-ZBS,Kaiserstraße 12,76131,Karlsruhe,Germany [3]Freiburg Materials Research Center,Stefan-Meier-Straße 21,79104,Freiburg,Germany [4]University of Freiburg,Physics Department,Hermann-Herder-Straße 3,79104 Freiburg,Germany

出　　处：《Friction》2014年第2期193-208,共16页摩擦（英文版）

基　　金：supported by the BMWi with the Progect Pegasus II(M.M.)and by the European Commission(Marie-Curie IOF 272619 for L.P.).Simulations were carried out at the Jülich Super-computing Centre(JSC).

摘　　要：Tetrahedral amorphous carbon coatings have the potential to significantly reduce friction and wear between sliding components.Here,we provide atomistic insights into the evolution of the sliding interface between naked and hydrogen-passivated ta-C sliding partners under dry and lubricated conditions.Using reactive classical atomistic simulations we show that sliding induces a sp3 to sp2 rehybridization and that the shear resistance is reduced by hydrogen-passivation and hexadecane-lubrication-despite our finding that nanoscale hexadecane layers are not always able to separate and protect ta-C counter surfaces during sliding.As asperities deform,carbon atoms within the hexadecane lubricant bind to the ta-C sliding partners resulting in degradation of the hexadecane molecules and in increased material intermixing at the sliding interface.Hydrogen atoms from the passivation layer and from the hexadecane chains continue to be mixed within a sp2 rich sliding interface eventually generating a tribo-layer that resembles an a-C:H type of material.Upon separation of the sliding partners,the tribo-couple splits within the newly formed sp2 rich a-C:H mixed layer with significant material transfer across the sliding partners.This leaves behind a-C:H coated ta-C surfaces with dangling C bonds,linear C chains and hydrocarbon fragments.

关 键 词：Atomic-scale simulations DLC LUBRICATION HEXADECANE passivation sliding mixed layer wear 

分 类 号：TG1[金属学及工艺—金属学]