Transition-Metal-Catalyzed Synthesis of Chiral Allylboronates  

作　　者：Wenbo Ming Xiaocui Liu Lujia Mao Xiao Gu Qing Ye 

机构地区：[1]Department of Chemistry,Southern University of Science and Technology,Shenzhen,Guangdong 518055,China

出　　处：《Chinese Journal of Chemistry》2021年第6期1716-1725,共10页中国化学（英文版）

基　　金：NSFC(Grant No.22071095);National Young Talents Program and SUSTech for financial support.

摘　　要：Since the pioneering work on Cr(Ⅲ)-catalyzed enantioselective[4+2]/allylboration reported by Hall and co-workers,a variety of catalytic methodologies for the asymmetric allylic borylation reactions have been developed to provide chiral allylboronates bearing a wide range of functional groups.This review article describes recent advances in transition-metal catalyzed preparation of chiral allylboronates,especially on those in the past three years,and with the emphasis on the aspect of asymmetric catalysis.According to the mechanism of achieving the chemo-,regio-,stereo-and enantioselectivities,the discussion is divided in two parts:substrate-controlled and catalyst-controlled synthesis.

关 键 词：Allylboronates Homoallyl Alcohols Asymmetric Synthesis Homogeneous Catalysis Transition Metals 

分 类 号：O62[理学—有机化学]