Transition-Metal-Catalyzed Carbon-Carbon Bond Activation in Asymmetric Synthesis  

作　　者：Xiufen Bi Qiuchi Zhang Zhenhua Gu Xiufen Bi;Qiuchi Zhang;Zhenhua Gu

机构地区：[1]Ocean College,Minjiong University Fuzhou,Fujian,350108,China [2]Hefei National Laboratory for Physical Science at the Microscale,and Department of Chemistry,Center for Excellence in Molecular Synthesis,University of Science and Technology of China,96 Jinzhai Road,Hefei,Anhui 230026,China

出　　处：《Chinese Journal of Chemistry》2021年第5期1397-1412,共16页中国化学（英文版）

基　　金：financial support from NSFC(92056102,21871241);Fundamental Research Funds for the Central Universities(WK2060190086).

摘　　要：Catalytic asymmetric transformations involving carbon-carbon bond cleavages open intriguing strategies for the synthesis of chiral complex molecules.The transient organometallic species mainly generate from the oxidative addition of cyclic compounds with low valence metals or from β-carbon elimination of tert-alkoxyl metals.This overview covers the recent advances in transition-metal-catalyzed carbon-carbon bond activation in asymmet-ric synthesis.

关 键 词：Carbon-carbon activation TRANSITION-METAL Asymmetric catalysis Asymmetric synthesis Ring-opening reaction 

分 类 号：O62[理学—有机化学]