基于聚烯烃的多嵌段共聚物合成方法研究进展  

Progress on the Synthesis of Polyolefin Multi-Block Copolymers

作　　者：陈艳君[1,2] 师奇松 Yanjun Chen;Qisong Shi(Zhejiang Collaborative Innovation Center for High Value Utilization of Byproducts from Ethylene Project,Ningbo Polytechnic,Ningbo 315800,China;College of Chemical Engineering,Ningbo Polytechnic,Ningbo 315800,China;College of Material Science and Engineering,Beijing Institute of Petrochemical Technology,Beijing 102617,China)

机构地区：[1]宁波职业技术学院乙烯工程副产物高质化利用浙江省应用技术协同创新中心,浙江宁波315800 [2]宁波职业技术学院化学工程学院,浙江宁波315800 [3]北京石油化工学院材料科学与工程学院,北京102617

出　　处：《高分子材料科学与工程》2021年第5期132-140,共9页Polymer Materials Science & Engineering

基　　金：浙江省教育厅一般科研项目(Y201941131);浙江省2019年度高校国内访问工程师“校企合作项目”(FG2019041);北京市自然科学基金资助项目(2172023);宁波职业技术学院乙烯工程副产物高质化利用浙江省应用技术协同创新中心2018-2019年度开放课题(NZXT2018308)。

摘　　要：聚烯烃是世界上产量和消费量最高的合成高分子材料,用途广泛,其多嵌段共聚物更具有特殊的性能。基于聚烯烃的多嵌段共聚物近年来所受到广泛关注,文中将从合成方法角度出发,系统综述基于聚烯烃的多嵌段共聚物的制备方法,重点介绍采用活性配位聚合、链穿梭聚合、烯烃复分解反应以及基于链行走机理的烯烃配位聚合合成嵌段数目大于3的聚烯烃基多嵌段共聚物的方法。Polyolefins are the largest volume and consumption polymers in the world today and their applications are wide.Block copolymers usually display special properties due to their special architectures.Polyolefin-based multi-block copolymers have attracted much attentions in recent years.The synthetic methods of polyolefin-based multi-block copolymers with more than 3 blocks were reviewed.Four synthetic methods were mainly introduced:living coordination polymerization,chain shuttling polymerization,olefin metathesis of polymers containing double bonds,olefin coordination polymerization based on chain-walking mechanism.

关 键 词：聚烯烃 多嵌段共聚物 配位活性聚合 链穿梭聚合 烯烃复分解反应 基于链行走机理的烯烃配位聚合 

分 类 号：TQ325.1[化学工程—合成树脂塑料工业]