One-Step, Solvothermal Synthesis of Graphene-CdS and Graphene-ZnS Quantum Dot Nanocomposites and Their Interesting Photovoltaic Properties  

作　　者：Ping Wang Tengfei Jiang Chengzhou Zhu Yueming Zhai Dejun Wang Shaojun Dong 

机构地区：[1]State Key Laboratory of Electroanalytical Chemistry,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China [2]College of Chemistry,Jilin University,Changchun 130012,China

出　　处：《Nano Research》2010年第11期794-799,共6页纳米研究（英文版）

基　　金：This work was supported by the National Natural Science Foundation of China(No.20820102037);the 973 Project(Nos.2009CB930100 and 2010CB933600);Dr.Ping Wang gratefully acknowledges partial financial support from the China Postdoctoral Science Foundation(No.20090461047);973 Project(No.2007CB613303).

摘　　要：The synthesis of graphene-semiconductor nanocomposites has attracted increasing attention due to their interesting optoelectronic properties.However the synthesis of such nanocomposites,with decorated particles well dispersed on graphene,is still a great challenge.This work reports a facile,one-step,solvothermal method for the synthesis of graphene-CdS and graphene-ZnS quantum dot nanocomposites directly from graphene oxide,with CdS and ZnS very well dispersed on the graphene nanosheets.Photoluminescence measurements showed that the integration of CdS and ZnS with graphene significantly decreases their photoluminescence.Transient photovoltage studies revealed that the graphene-CdS nanocomposite exhibits a very unexpected strong positive photovoltaic response,while separate samples of graphene and CdS quantum dots(QDs)of a similar size do not show any photovoltaic response.

关 键 词：GRAPHENE CdS ZNS quantum dots charge transfer photovoltaic 

分 类 号：O61[理学—无机化学]