Formation and Optical Properties of ZnO:ZnFe_(2)O_(4) Superlattice Microwires  

作　　者：Yun Li Guozhang Dai Chunjiao Zhou Qinglin Zhang Qiang Wan Limin Fu Jianping Zhang Ruibin Liu Chuanbao Cao Anlian Pan Yunhong Zhang Bingsuo Zou 

机构地区：[1]State Key Laboratory of Chemo/biosensing and Chemometrics(CBSC),Hunan University,Changsha 410082,China [2]School of Materials Science and Engineering(MSE),Beijing Institute of Technology,Beijing 100081,China [3]Chemistry Department,Renmin University of China,Beijing 100872,China

出　　处：《Nano Research》2010年第5期326-338,共13页纳米研究（英文版）

基　　金：The authors thank the National Natural Science Foundation of China(NSFC)of China(Nos.90606001,20873039,and 90406024)for financial support.

摘　　要：Pure ZnO hexagonal microwires and Fe(Ⅲ)-doped ZnO microwires(MWs)with a novel rectangular cross section were synthesized in a confined chamber by a convenient one-step thermal evaporation method.An oriented attachment mechanism is consistent with a vapor-solid growth process.Photoluminescence(PL)and Raman spectroscopy of the Fe(Ⅲ)-doped ZnO MWs and in situ spectral mappings indicate a quasi-periodic distribution of Fe(Ⅲ)along a one-dimensional(1-D)superlattice ZnO:ZnFe_(2)O_(4) wire,while PL mapping shows the presence of optical multicavities and related multimodes.The PL spectra at room temperature show weak near-edge doublets(376 nm and 383 nm)and a broad band(450-650 nm)composed of strong discrete lines,due to a 1-D photonic crystal structure.Such a 1-D coupled optical cavity material may find many applications in future photonic and spintronic devices.

关 键 词：ZNO superlattice microwire MICRO-PHOTOLUMINESCENCE micro-Raman spectroscopy 

分 类 号：TN0[电子电信—物理电子学]