Cooperative Assembly of Asymmetric Carbonaceous Bivalve-Like Superstructures from Multiple Building Blocks  

作　　者：Lei Xie Haiyan Wang Chunhong Chen Shanjun Mao Yiqing Chen Haoran Li Yong Wang 

机构地区：[1]Advanced Materials and Catalysis Group,Institute of Catalysis,Zhejiang University,Hangzhou 310028,China

出　　处：《Research》2018年第1期44-53,共10页研究（英文）

基　　金：Financial support from the National Key R&D Program of China(2016YFA0202900);the National Natural Science Foundation of China(21622308,91534114);the Key Program Supported by the Natural Science Foundation of Zhejiang Province,China(LZ18B060002);and the Fundamental Research Funds for the Central Universities(2017XZZX002-16)is greatly appreciated.

摘　　要：Te assembly of superstructures from building blocks is of fundamental importance for engineering materials with distinct morphologies and properties,and deepening our understanding of self-assembly processes in nature.Up to now,it is still a great challenge in materials science to construct multiple-component superstructure with unprecedented architectural complexity and symmetry from molecular.Here,we demonstrate an improved one-pot hydrothermal carbonization of biomass strategy that is capable of fabricating unprecedented asymmetric carbonaceous bivalve-like superstructures with in suit generated solid particles and ordered porous polymers as two kinds of building blocks.In our system,diferent building blocks can be controllably generated,and they will assemble into complex superstructures through a proposed“cooperative assembly of particles and ordered porous polymers”mechanism.We believe that this assembly principle will open up new potential felds for the synthesis of superstructures with diverse morphologies,compositions,and properties.

关 键 词：properties. mechanism SYMMETRY 

分 类 号：O62[理学—有机化学]