A single Eu^(2+)-activated high-color-rendering oxychloride white-light phosphor for white-light-emitting diodes  

作　　者：Peng-Peng Dai Cong Li Xin-Tong Zhang Jun Xu Xi Chen Xiu-Li Wang Yan Jia Xiaojun Wang Yi-Chun Liu 

机构地区：[1]Center for Advanced Optoelectronic Functional Materials Research,and Key Laboratory for UV-Emitting Materials and Technology of Ministry of Education,Northeast Normal University,5268 Renmin Street,Changchun 130024,China [2]Department of Chemistry,University of Zurich,The X-ray Crystallography Facility and The Linden Research Group,Winterthurerstrasse,190 CH-8057 Zurich,Switzerland [3]School of Life Sciences,Northeast Normal University,5268 Renmin Street,Changchun 130024,China [4]Department of Physics,Georgia Southern University,Statesboro,GA 30460,USA

出　　处：《Light(Science & Applications)》2016年第1期677-685,共9页光（科学与应用)（英文版）

基　　金：supported by theNational Natural Science Foundations of China(Grant No.51302034,11304035,51372036,31271442,and 91233204);the National Basic Research Program(2012CB933703);the Fundamental Research Funds for the Central Universities(Grant No.12QNJJ007,12SSXM001);the International Science&Technology Cooperation Program of China(2013DFG50150);111 project(No.B13013).

摘　　要：Single-phased,high-color-rendering index(CRI)white-light phosphors are emerging as potential phosphor-converted white-light-emitting diodes(WLEDs)and as an alternative to blends of tricolor phosphors.However,it is a challenge to create a high CRI white light from a single-doped activator.Here,we present a high CRI(Ra 591)white-light phosphor,Sr_(5)(PO_(4))_(3-x)(BO_(3))_(x)Cl:Eu^(2+),composed of Sr5(PO4)3Cl as the beginning member and Sr_(5)(BO_(3))_(3)Cl as the end member.This work utilized the solid-solution method,and tunable Eu^(2+) emission was achieved.Color-tunable Eu^(2+) emissions in response to structural variation were observed in Sr_(5)(PO_(4))_(3-x)(BO_(3))_(x)Cl solid solutions.This was further confirmed using X-ray Rietveld refinement,electron paramagnetic resonance spectroscopy,and in the photoluminescence spectra.The color-tunable emissions included the white light that originated from the combination of the blue emission of Sr_(5)(PO_(4))_(3)Cl:Eu^(2+) and an induced Eu^(2+) yellow emission at approximately 550 nm in the solid solution.Importantly,the white-light phosphors showed a greater R9590.2 under excitation at 365 nm.This result has rarely been reported in the literature and is greater than that of(R9514.3)commercial Y_(3)A_(l5)O_(12):Ce^(3+)-based WLEDs.These findings demonstrate the great potential of Sr_(5)(PO_(4))_(3-x)(BO_(3))_(x)Cl:0.04Eu^(2+) as a white-light phosphor for near-UV phosphor-converted WLEDs.These results also provide a shortcut for developing a high CRI white-light phosphor from a single Eu^(2+)-doped compound.

关 键 词：high-color-rendering single Eu^(2+)-activated solid solution white-emitting phosphor 

分 类 号：O61[理学—无机化学]