二氯乙二肟合成及其含能衍生物研究进展  

Research Progress on the Synthesis of Dichloroglyoxime and Its Energetic Derivatives

作　　者：王荦荦 翟连杰[1,2] 杨晓哲 霍欢[1] 常海[1] 刘宁[1,2] WANG Luo-luo;ZHAI Lian-jie;YANG Xiao-zhe;HUO Huan;CHANG Hai;LIU Ning(Modern Chemistry Research Institution,Xi′an 710065,China;State Key Laboratory of Fluorine&Nitrogen Chemicals,Xi′an 710065,China)

机构地区：[1]西安近代化学研究所,陕西西安710065 [2]氟氮化工资源高效开发与利用国家重点实验室,陕西西安710065

出　　处：《含能材料》2021年第8期771-780,I0008,共11页Chinese Journal of Energetic Materials

基　　金：国家自然科学基金资助(21805224)。

摘　　要：二氯乙二肟是一种高效的工业杀菌剂,也是构建氮杂环骨架的重要原材料,可合成多种性能优异高氮含能材料。本文主要介绍了氯气法、N‐氯代琥珀酰亚胺(NCS)/二甲基甲酰胺(DMF)法以及NCS/DMF改进法等3种二氯乙二肟的合成方法,并比较了它们优缺点。系统阐述了基于二氯乙二肟的反应特性构建异噁唑、呋咱、氧化呋咱、双四唑以及噁二唑酮等氮杂环中间体的方法,同时,综述了相关含能材料的物化与爆轰性能。利用二氯乙二肟作为原料,有望设计、合成性能优异的新型含能材料,全面推动含能材料自主创新能力的提升。Dichloroglyoxime is an efficient industrial bactericide and an important starting material for construction of nitrogen heterocyclic framework,which can be utilized as a pivotal precursor for a variety of high nitrogen energetic materials with excellent performances.Three synthetic methods of dichloroglyoxime,such as chlorine method,NCS/DMF method and NCS/DMF improved method,were introduced,and their advantages and disadvantages were also discussed.Based on the reaction characteristics of dichloroglyoxime,the methods of constructing N‐heterocyclic frameworks,such as isoxazole,furoxan,furoxan,bistetrazole and oxadiazolone,were systematically described.Additionally,the physicochemical properties and detonation performances of typical energetic materials were also discussed.Using dichloroglyoxime as starting materials,it is expected to design and synthesize some new energetic materials with excellent performances,and comprehensively promote the innovation ability of energetic materials.

关 键 词：二氯乙二肟 制备方法 含能材料 合成 含能性能 

分 类 号：TJ55[兵器科学与技术—军事化学与烟火技术]