Metal-Organic Framework Membranes and Membrane Reactors:Versatile Separations and Intensified Processes  

作　　者：Yujie Ban Na Cao Weishen Yang 

机构地区：[1]State Key Laboratory of Catalysis,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,457 Zhongshan Road,Dalian 116023,China [2]University of Chinese Academy of Sciences,19A Yuquan Road,Beijing 100039,China

出　　处：《Research》2020年第1期122-134,共13页研究（英文）

基　　金：This work was supported by the National Natural Science Foundation of China(grants 21978283,21721004,and 21706249);the Strategic Priority Research Program of the Chinese Academy of Sciences(grant XDB17020400);LiaoNing Revitalization Talents Program(XLYC1801004);DICP(grant DICP I201946).

摘　　要：Metal-organic frameworks are an emerging and fascinating category of porous solids that can be self-assembled with metal-based cations linked by organic molecules.The unique features of MOFs in porosity(or surface areas),together with their diversity for chemical components and architectures,make MOFs attractive candidates in many applications.MOF membranes represent a long-term endeavor to convert MOF crystals in the lab to potentially industry-available commodities,which,as a promising alternative to distillation,provide a bright future for energy-efficient separation technologies closely related with chemicals,the environment,and energy.The membrane reactor shows a typical intensified process strategy by combining the catalytic reaction with the membrane separation in one unit.This review highlights the recent process of MOF-based membranes and the importance of MOF-based membrane reactors in relative intensified chemical processes.

关 键 词：SEPARATION DISTILLATION ATTRACTIVE 

分 类 号：O64[理学—物理化学]