Sol-Gel Template Synthesis and Photoluminescence Properties of (Pb_(0.5)Sr_(0.5))TiO_(3) Nanotube Arrays  

作　　者：JIANG Yan-Ping WANG Yu CHAN Lai Wa Helen TANG Xin-Gui ZHOU Yi-Chun 蒋艳平;王雨;陈王丽华;唐新桂;周益春(Key Laboratory of Low-Dimensional Materials and Application Technology,Xiangtan University,Xiangtan 411105;Department of Applied Physics and Materials Research Centre,Hong Kong Polytechnic University,Hung Hom,Kowloon,Hong Kong,China;School of Physics&Optoelectric Engineering,and Guangzhou Higher Education Mega Center,Guangdong University of Technology,Guangzhou 510006)

机构地区：[1]Key Laboratory of Low-Dimensional Materials and Application Technology,Xiangtan University,Xiangtan 411105 [2]Department of Applied Physics and Materials Research Centre,Hong Kong Polytechnic University,Hung Hom,Kowloon,Hong Kong,China [3]School of Physics&Optoelectric Engineering,and Guangzhou Higher Education Mega Center,Guangdong University of Technology,Guangzhou 510006

出　　处：《Chinese Physics Letters》2011年第7期278-281,共4页中国物理快报（英文版）

基　　金：by the Major Program of the National Natural Science Foundation of China under Grant No 11032010;the Opening Project Program of Key Laboratory of Low-Dimensional Materials and Application Technology(Ministry of Education);Xiangtan University,under Grant No DWKF0804.

摘　　要：Lead strontium titanate(Pb_(0.5)Sr_(0.5))TiO_(3)(PST)nanotube arrays are prepared by a sol-gel and spin-coating process using an anodic aluminium oxide template.The structure and morphology of the as-prepared sample are characterized by x-ray diffraction,scanning electron microscopy and transmission electron microscopy.The results show that the as-prepared PST sample possesses a perovskite structure with a relatively uniform diameter of about 200 nm.Photoluminescence(PL)spectrum of the sample shows emission bands centered at about 2.87 eV at room temperature,which consists of three intense emission sub-bands at 3.02,2.87 and 2.76 eV,respectively.The energy corresponding to the central PL peak is lower than the band-gap energy(3.2 eV)of PST bulk materials,which may originate from the size effect of the PST nanotube arrays.The multi-peaks in the PL spectrum may be attributed to the radiative recombination of trapped electrons and holes in tail and gap states induced by local defect and oxygen vacancies.The Raman scattering spectrum of the PST nanotube arrays,which are obviously broadened in comparison with the bulk materials,show that their phonon modes are in agreement with those allowed in the tetragonal phase.

关 键 词：TEMPLATE PEROVSKITE BANDS 

分 类 号：TB3[一般工业技术—材料科学与工程]