Role of Surface Hydrogen Bonds in Determining the Friction Behaviors of Hydrogenated Diamond-like Carbon Films  

作　　者：WANG Cheng-Bing SHI Jing GENG Zhong-Rong ZHANG Jun-Yan 王成兵;师晶;耿中荣;张俊彦(National Engineering Research Center for Technology and Equipment of Green Coating,Lanzhou Jiaotong University,Lanzhou 730070;State Key Laboratory of Solid Lubrication,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000)

机构地区：[1]National Engineering Research Center for Technology and Equipment of Green Coating,Lanzhou Jiaotong University,Lanzhou 730070 [2]State Key Laboratory of Solid Lubrication,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000

出　　处：《Chinese Physics Letters》2012年第5期189-192,共4页中国物理快报（英文版）

基　　金：Supported by the National Natural Science Foundation of China under Grant Nos 51005110 and 11104126;China Postdoctoral Science Foundation under Grant No 20090450846;the Research Fund for the Doctoral Program of Higher Education of China under Grant No 20096204120002。

摘　　要：Friction behaviors of hydrogenated diamond-like carbon (H-DLC) films are investigated on a ball-on-disk type tribometer in dry N2 and dry vacuum.The result shows that the friction behaviors of the H-DLC films are very sensitive to the testing environment,the H-DLC films exhibit a very low friction coefficient of 0.016 in dry N2,and similarly in an inert gas the friction coefficient increases to about 0.063 in dry vacuum.Combining the testing conditions,friction results,SEM and XPS investigation,it is concluded that the friction behaviors of the hydrogenated DLC films are associated with surface hydrogen of the H-DLC films and are dictated by whether or not hydrogen bonds are formed between the transfer films/H-DLC films at the sliding interface.A hydrogen-induced hydrogen bond model is proposed to interpret the friction behaviors of hydrogenated DLC films in different environments.

关 键 词：FRICTION HYDROGEN VACUUM 

分 类 号：TG1[金属学及工艺—金属学]