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作 者:HAN Peng CHEN Xi LI He-ping 韩鹏;陈熙;李和平(Department of Engineering Mechanics,Tsinghua University,Beijing 100084)
机构地区:[1]Department of Engineering Mechanics,Tsinghua University,Beijing 100084
出 处:《Chinese Physics Letters》1999年第3期193-195,共3页中国物理快报(英文版)
基 金:Supported by the National Natural Science Foundation of China under Grant Nos.59676011 and 59836220.
摘 要:Two quite different Saha equations modified to a two-temperature plasma were proposed and employed in many literatures.In order to clear up this confusion phenomenon lasted for a few decades in the community of thermal plasma science and technology,this paper re-examines the thermodynamic derivation of the two-temperature Saha equations.It is pointed out that the modified Saha equation deduced by using the minimum Gibbs or Helmholtz free energy is incorrect for the two-temperature plasma.Instead,a more rigorous derivation is presented here from the basic thermodynamic principle that the entropy in an isolated system always assumes its maximum value at chemical equilibrium.
关 键 词:DERIVATION THERMODYNAMIC assume
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