Challenges and Recent Developments of Photoflow-Reversible Deactivation Radical Polymerization(RDRP)  

作　　者：Zhuo-Ran Zhong Yi-Nan Chen Yang Zhou Mao Chen 

机构地区：[1]State Key Laboratory of Molecular Engineering of Polymers,Department of Macromolecular Science,Fudan University,Shanghai 200433,China

出　　处：《Chinese Journal of Polymer Science》2021年第9期1069-1083,共15页高分子科学（英文版）

基　　金：This work was financially supported by the National Natural Science Foundation of China(Nos.21704016 and 21971044).

摘　　要：Photo-controlled reversible-deactivation radical polymerizati on(photo-RDRP)has been investigated as a"green"and spatiotem-porally controlling pathway for polymer synthesis.While the combination of photo-RDRP and flow chemistry has offered opportunities to increase light intensity and enable uniform light irradiation,problems associated with flow approaches still remain for photoflow-RDRP,which has hindered merging flow polymerization with other cutting-edge techniques.Herein,we summarize challenges and recent achievements in photoflow-RDRP including the development of(a)droplet/slug-flow to regulate reside nee time distribution,(b)mixing techniques to tailor polymer,(c)polymerization in duced self-assembly,and(d)computer-aided synthesis.We hope this work will provide in formative knowledge to people in related fields and stimulate novel ideas to promote polymer synthesis in both academia and industry.

关 键 词：Controlled radical polymerization RDRP PHOTOPOLYMERIZATION Flow chemistry Flow polymerization 

分 类 号：TQ316.322[化学工程—高聚物工业]