The Application of Controlled/Living Radical Polymerization in Modification of PVDF-based Fluoropolymer  

作　　者：Hong-Hong Gong Ying Zhang Yi-Pin Cheng Ming-Xin Lei Zhi-Cheng Zhang 

机构地区：[1]Xi'an Key Laboratory of Sustainable Energy Materials Chemistry,Department of Applied Chemistry,School of Chemistry,Xi'an Jiaotong University,Xi'an 710049,China [2]Xi'an Jiaotong University Suzhou Academy,Suzhou 215123,China

出　　处：《Chinese Journal of Polymer Science》2021年第9期1110-1126,共17页高分子科学（英文版）

基　　金：This work was financially supported by the National Natural Science Foundation of China(Nos.92066204,52003214,51773166 and 51603167);China Postdoctoral Science Foundation Funded Project(Nos.2019M663699 and 2020T130507);Key Laboratory Construction Program of Xi'an Municipal Bureau of Science and Technology(No.201805056ZD7CG40);Natural Science Foundation of Jiangsu Province(No.BK2020245);Suzhou Science and Technology Project(No.SYG202028);the Fundamental Research Funds for the Central Universities(No.xzy012020035).

摘　　要：Fluorinated polymers are important materials that are widely used in many areas as taking the advantage of inertness to chemical corrosion,prominent weather resista nee,low flammability,and good thermal stability.Poly(vinylidene fluoride)(PVDF)based fluoropolymers is the most commontype of commercial fluoropolymer especially used as dielectric materials.However,there are always some shortcomings in practical applications,so it is necessary to modify PVDF-based fluoropolymers for better application.Controlled/living radical polymerization(CRP)and related techniques have become a powerful approach to tailoring the chemical and physical properties of materials and have given rise to great advances in modification of PVDF-based fluoropolymers.

关 键 词：CRP PVDF-based fluoropolymers ATRP RAFT 

分 类 号：TQ316.322[化学工程—高聚物工业]