Synthesis and properties of novel nitro-based thermally stable energetic compounds  

作　　者：Łukasz Gutowski Stanisław Cudziło 

机构地区：[1]Military University of Technology,Faculty of Advanced Technologies and Chemistry,Gen.Sylwestra Kaliskiego 2 Street,00-908,Warsaw,Poland

出　　处：《Defence Technology（防务技术）》2021年第3期775-784,共10页Defence Technology

基　　金：Financial support of this work by the Military University of Technology in Warsaw is gratefully acknowledged。

摘　　要：This paper reviews the achievements in the field of synthesis of new thermally resistant explosive compounds in the years 2009 through 2019. The performance characteristics of these compounds(sensitivity, thermal decomposition parameters, and detonation parameters) were compared with those of 1,3,5-triamino-2,4,6-trinitrobenzene, which still seems to be an unrivalled model of a thermally resistant and generally low-sensitivity explosive material. New thermally stable explosives(TSEs) were found among macromolecular compounds with tri-and dinitrophenyl groups, nitro and amine-nitro derivatives of azoles, and polynitro derivatives of calixarenes. Some of them match TATB in terms of thermal resistance and additionally have higher detonation parameters.

关 键 词：Heat resistant explosives Detonation parameters SYNTHESIS NITRATION 

分 类 号：TQ560.1[化学工程—炸药化工]