CS_(2)和COS低温水解催化剂及反应机理研究进展  

Research progress of CS_(2) and COS low-temperature hydrolysis catalyst and reaction mechanism

作　　者：赵新来 李汝晗 周广林[2] 张现策 Zhao Xinlai;Li Ruhan;Zhou Guanglin;Zhang Xiance(Zibo Luhua Hongjin New Material Co.,Ltd.,Zibo Shandong 255411,China;College of New Energy and Materials,China University of Petroleum-Beijing,Beijing 102249,China)

机构地区：[1]鲁华泓锦新材料股份有限公司,山东淄博255411 [2]中国石油大学(北京)新能源与材料学院,北京102249

出　　处：《石油化工》2021年第8期815-820,共6页Petrochemical Technology

摘　　要：综述了近年来纳米纤维、类水滑石、单原子和三维有序大孔材料等新型材料催化剂用于CS_(2)、羰基硫(COS)水解反应的发展近状。讨论了CS_(2)与COS水解反应机理,并结合量子化学方法分析了碱性活性位点对CS_(2)和COS水解反应的促进作用。The recent development of new material catalysts including nanofibers,hydrotalcitelike materials,single atom,and three dimensional ordered macroporous materials for the hydrolysis of CS_(2) and carbonyl sulfide(COS)is reviewed.In addition,the reaction mechanism of the hydrolysis of CS_(2) and COS is discussed,and the promotion of the hydrolysis of CS_(2) and COS by alkaline active sites is analyzed in combination with quantum chemical methods.

关 键 词：二硫化碳 羰基硫 水解催化剂 计算化学 

分 类 号：TQ426.83[化学工程]