杂环酰基吡唑啉酮缩氨基咔唑光功能基元新型席夫碱的合成与表征  

Synthesis and Characterization of the Schiff base Derived from PMBP and Amines

作　　者：吴琼[1] 金铜音[1] 梁明星 张恒强[1] Wu Qiong;Jin Tongyin;Liang Mingxing;Zhang Hengqiang(Department of Chemistry and Chemical Engineering,Hebei Normal University for Nationalities,Hebei,067000)

机构地区：[1]河北民族师范学院化学与化工学院,河北067000

出　　处：《当代化工研究》2021年第16期40-42,共3页Modern Chemical Research

基　　金：承德市科技局项目(201804A057);河北民族师范学院项目(QN2018005)。

摘　　要：本论文设计咔唑为原料制备氨基咔唑,然后再将呋喃甲酰氯和氨基咔唑相结合,生成一种杂环酰基吡唑啉酮和咔唑双光功能的新型希夫碱1-苯基-3-甲基-4-呋喃甲酰基-吡唑啉酮-5缩9-(4-氨基苯基),将最后的产品的结构经红外光谱、紫外光谱对这种新型的希夫碱晶体结构进行初步研究,将其与酰基吡唑啉酮或咔唑功能基元相比较,合成的新型希夫碱晶体表现出的特殊的电子结构使其有望用于分子光电器件领域。This paper designs amino carbazole carbazole as raw material preparation,and then combining furoyl chloride and amino carbazole,containing reaction to generate a new type of acyl pyrazolone and carbazole light function of primitive new schiff base 1-phenyl-3-methyl-4-furan formyl-pyrazolone-5 and 3-amino-9-ethyl carbazole.The final product structure were confirmed by infrared spectrum,ULTRAVIOLET spectrum and compared with acylpyrazolone or carbazole functional units,the new schiff base crystal showed special electronic structure,which made it possible to be used in the field of molecular optoelectronic devices.

关 键 词：咔唑 希夫碱 合成 

分 类 号：O625.63[理学—有机化学] O626[理学—化学]