新型非共价键构象锁定型小分子的合成及性能研究  

Synthesis and Properties of Novel Non-covalent Conformation Locked Small Molecules

作　　者：王梅 李宇翔 王英英 秦红梅 杨建业[1] WANG Mei;LI Yu-xiang;WANG Ying-ying;QIN Hong-mei;YANG Jian-ye(School of Materials Science and Engineering, Xi'an University of Science and Technology,Xi'an 710054, China)

机构地区：[1]西安科技大学材料科学与工程学院,陕西西安710054

出　　处：《合成化学》2021年第8期673-678,共6页Chinese Journal of Synthetic Chemistry

基　　金：国家自然科学基金资助项目(21905225);陕西省自然科学基础研究计划(2019JQ-244,2019JQ-076)。

摘　　要：以2,5-二溴烷氧基苯为起始原料,设计并合成了以烷氧基取代苯环为核,双氰基茚满二酮为端基,噻吩或并噻吩为π桥的两个新型非共价键构象锁定型有机小分子PTIC和PTTIC,其结构和性能经^(1)H NMR,^(13)C NMR,UV,CV,DSC和GIWAXS表征。结果表明:在分子内非共价键作用力作用下,PTIC和PTTIC均表现出良好的共平面性和结晶性。Using 2,5-dibromoalkoxybenzene as starting material,two novel noncovalent conformation locked organic small molecules PTIC and PTTIC were designed and synthesized with alkoxy substituted benzene ring as core,dicyanidinone as end group and thiophene or thienothiophene asπbridge.The structures and performances of PTIC and PTTIC were characterized by ^(1)H NMR,^(13)C NMR,UV,CV,DSC and GIWAXS.The results show that the existence of non-covalent bond forces makes the two small molecules show good coplanarity and crystallinity.

关 键 词：2 5-二溴烷氧基苯 构象 非共价键作用力 烷氧基苯 噻吩 合成 结晶性 

分 类 号：TB322[一般工业技术—材料科学与工程] O62[理学—有机化学]