1^(2),5^(2)-二羟基-1^(5),5^(5)-二甲基-1^(4),1^(6),3^(4),3^(6),5^(4),5^(6),7^(4),7^(6)-八硝基-2,4,6,8-四氧桥连-1,3,5,7(1,3)-杯[4]芳烃的合成  

Synthesis of 1^(5),5^(5)-Dimethyl-1^(4),1^(6),3^(4),3^(6),5^(4),5^(6),7^(4),7^(6)-octanitro-2,4,6,8-tetraoxa-1,3,5,7(1,3)-tetrabenzenacyclooctaphane-12,52-diol

作　　者：邹芳芳 张行程 张梦娇 胡文祥[1,3,4] ZOU Fang-fang;ZHANG Xing-cheng;ZHANG Meng-jiao;HU Wen-xiang(School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan 430205, China;Green Catalysis & Synthesis Key Laboratory of Xinyang City, College of Chemistry and Chemical Engineering, XinYang Normal University, Xinyang 464000, China;Jingdong Xianghu Microwave Chemistry Union Laboratory, Beijing Shenjian Tianjun Academy of Medical Sciences, Beijing 101601, China;Aerospace Systems Division, Strategic Support Troops, Chinese People’s Liberation Army, Beijing 100101, China)

机构地区：[1]武汉工程大学化工与制药学院,湖北武汉430205 [2]信阳师范学院化学化工学院信阳市绿色催化和合成重点实验室,河南信阳464000 [3]北京神剑天军医学科学院京东祥鹄微波化学联合实验室,北京101601 [4]中国人民解放军战略支援部队航天系统部,北京100101

出　　处：《合成化学》2021年第8期701-704,共4页Chinese Journal of Synthetic Chemistry

基　　金：河南省科技攻关项目(182102310277);河南省科技智库项目(HNKJZK-2020-34C);河南省自然科学基金资助项目(202300410337);信阳师范学院重大预研项目(20078,19162)。

摘　　要：以1,5-二氟-2,4-二硝基苯和3,4,5-三甲氧基甲苯为起始原料,经环化、甲基化、硝化和去甲基化反应,合成了一种新型杯芳烃衍生物,其结构经^(1)H NMR,^(13)C NMR和元素分析表征。A novel calixarene derivatives was synthesized by cyclization,methylation,nitration,and demethylation reactions using 1,5-difluoro-2,4-dinitrobenzene and 3,4,5-trinitrotoluene as starting materials,The structure was characterized by ^(1)H NMR,^(13)C NMR,and elemental analysis.

关 键 词：耐热炸药 杯芳烃 含能材料 环化 硝化 合成 

分 类 号：O62[理学—有机化学]