环氧树脂辅助制备LiNi1/3Co1/3Mn1/3O2及其储锂性能  

Preparation of LiNiCoMnO by the Assistant of Epoxy Resin and Its Lithium Storage Performance

作　　者：王秀利 朱铮瑶 陈卓新 黄俊杰[3] Wang Xiuli;Zhu Zhengyao;Chen zhuoxin;Huang Junjie(Technical Center Wolong Electric Group Zhejiang Dengta Power Source Co.,Ltd.,Shaoxing 312000;College of Chemistry and Chemical Engineering,Taiyuan University of Technology,Taiyuan 030000;College of Chemistry and Chemical Engineering,Shaoxing University,Shaoxing 312000,China)

机构地区：[1]卧龙电气集团浙江灯塔电源有限公司技术中心,浙江绍兴312000 [2]太原理工大学化学化工学院,山西太原030000 [3]绍兴文理学院化工学院,浙江绍兴312000

出　　处：《广东化工》2021年第13期29-30,共2页Guangdong Chemical Industry

摘　　要：采用环氧树脂来均匀分散Li+,Co2+,Mn2+和Ni2+,并通过环氧树脂低温固化来维持离子均匀分散,续以空气中充分煅烧制备LiNi1/3Co1/3Mn1/3O2材料。电化学研究显示,850℃下制得的材料具有更好的充放电性能,0.2℃倍率下的首次充放电容量分别达到186.4和135.1mAh·g-1。In this work,LiNi1/3Co1/3Mn1/3O2 is prepared by one-step method of calcinating the precursor at air atmosphere,which is obtained by solidifying epoxy resin solution containing Li+,Co2+,Mn2+ and Ni2+ ions in well mixing state.Electrochemical analysis show that the sample obtained at 850℃ displays an excellent charge/discharge performance,at 0.2 C the initial charge and discharge capacities can be 186.4 and 135.1 mAh ·g-1 respectively.

关 键 词：LINI1/3CO1/3MN1/3O2 环氧树脂 正极材料 锂离子电池 

分 类 号：TQ[化学工程]