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作 者:黄国桃 桂源 李玉才 吴鑫 冯新星 邓建平[1] 王操 潘凯[1] HUANG Guotao;GUI Yuan;LI Yucai;WU Xin;FENG Xinxing;DENG Jianping;WANG Cao;PAN Kai(College of Materials Science and Engineering,Beijing University of Chemical Technology,Beijing 100029,China;De Zhou Xin Hua Run Technology Co,Ltd,Dezhou 253000,China;Institute of Quartermaster Engineering and Technology of System Engineering Research Institute,Academy of Military Sciences,PLA,Beijing 100010,China)
机构地区:[1]北京化工大学材料科学与工程学院,北京100029 [2]德州市鑫华润科技股份有限公司,山东德州253000 [3]军事科学院系统工程研究院军需工程技术研究所,北京100010
出 处:《中国塑料》2021年第9期1-7,共7页China Plastics
基 金:山东省重大科技创新项目(2019JZZY020218)。
摘 要:选用乙烯⁃醋酸乙烯共聚物(EVA)与市面上制备工艺最成熟的聚酰胺12弹性体(PEBAX)共混挤出,制得EVA/PEBAX复合材料,再使用模压成型工艺将其进行化学发泡,制备出新型的EVA/PEBAX微孔发泡材料。结果表明,EVA/PEBAX复合材料可成功进行化学发泡,相比于传统EVA发泡材料,其性能有所提升,当PEBAX含量为5%(质量分数,下同)、发泡剂含量为1%时,性能最优;该聚酰胺弹性体基发泡材料不仅性能更优,同时还兼具了成本低的优势,具有替代传统EVA发泡鞋材的前景。In this paper,ethylene⁃vinyl⁃acetate copolymer(EVA)/nylon elastomer compounds were prepared through melt extrusion using the most popular commercial product of PEBAX nylon 12.The resultant compounds were foamed to prepare a new type of EVA/nylon 12 microporous foaming materials.The experimental results indicated that the EVA/nylon 12 compounds were foamed successfully through a chemical method,and their foaming materials achieved an improvement in performance in comparison with the traditional EVA ones.The EVA/nylon 12 foaming materials ob⁃tained an optimal performance at a nylon 12 content of 5 wt%and a foaming agent content of 1 wt%.This type of nylon elastomer⁃based foaming materials has superiority in cost and performance,therefore it has a good prospect for the replacement of traditional EVA foamed materials used in shoes.
关 键 词:聚酰胺弹性体 乙烯⁃醋酸乙烯共聚物 化学发泡 力学性能
分 类 号:TQ323.6[化学工程—合成树脂塑料工业]
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