聚碳酸酯合成技术研究进展  

Progress on Synthesis Technology of Polycarbonate

作　　者：曾伟华 刘俊逸 谢海生 邹永春 吴芮 张爱民[2] 武建勋[2] Weihua Zeng;Junyi Liu;Haisheng Xie;Yongchun Zou;Rui Wu;Aimin Zhang;Jianxun Wu(Shanghai Sinochem Technology Co.,Ltd.,Shanghai 200120,China;State Key Laboratory of Polymer Materials Engineering,Polymer Research Institute of Sichuan University,Chengdu 610065,China)

机构地区：[1]上海中化科技有限公司,上海200120 [2]高分子材料工程国家重点实验室四川大学高分子研究所,四川成都610065

出　　处：《高分子材料科学与工程》2021年第7期183-190,共8页Polymer Materials Science & Engineering

基　　金：四川大学中海油惠州石化有限公司项目(18H0393)。

摘　　要：概要地介绍了聚碳酸酯的合成技术,重点对非光气法进行了介绍,比较了非光气法相对于光气法的优缺点。按照不同的合成路径对非光气法进行了全面阐述,阐明了双酚A聚碳酸酯非光气化、低碳、减排的绿色和可持续发展的化工工艺技术是聚碳酸酯合成技术发展的方向。另一方面,共聚聚碳酸酯和脂肪族聚碳酸酯由于其有别于传统聚碳酸酯的阻燃、绿色、环保以及可降解等性能,逐渐受到各国研究人员的重视。The synthesis technology of polycarbonate was briefly introduced,and stressed the non-phosgene method.The advantages and disadvantages of the non-phosgene method were compared with the phosgene method.The non-phosgene method was described comprehensively according to different synthetic routes.It is expounded that the non-phosgene,low-carbon,emission reduction,green and sustainable chemical technology of bisphenol A polycarbonate is the development direction of polycarbonate synthesis technology.On the other hand,copolymer polycarbonate and aliphatic polycarbonate have gradually drawn attention due to their flame-retardant,green,environmentally friendly and biodegradability,which are different from traditional polycarbonate.

关 键 词：聚碳酸酯 碳酸二甲酯 碳酸二苯酯 二氧化碳 合成 

分 类 号：TQ323.41[化学工程—合成树脂塑料工业]