Perspective on synthesis of high-energy-density fuels:From petroleum to coal-based pathway  

作　　者：Chengxiang Shi Jisheng Xu Lun Pan Xiangwen Zhang Ji-Jun Zou 

机构地区：[1]Key Laboratory for Green Chemical Technology of the Ministry of Education,School of Chemical Engineering and Technology,Tianjin University,Tianjin 300072,China [2]Collaborative Innovative Center of Chemical Science and Engineering(Tianjin),Tianjin 300072,China

出　　处：《Chinese Journal of Chemical Engineering》2021年第7期83-91,共9页中国化学工程学报（英文版）

基　　金：supported by the National Natural Science Foundation of China(21978200);Scientific Research of the Ministry of Education of China(6141A02033522)。

摘　　要：High-energy–density(HED)fuel is specifically pivotal to improve the performance of volume-limited aircrafts.The widely used HED fuels composed of polycyclic hydrocarbons are mainly synthesized from petroleum feedstocks.In order to ensure abundant supply,alternative resources such as coal should be considered.Herein,we summarize the synthesis methods and properties of typical HED fuels by using petroleum-derived cyclopentadiene(CPD)as key feedstock through dimerization,cycloaddition,hydrogenation and isomerization/photoisomerization reactions,and then propose a blueprint for synthesizing HED fuels from coal.The method to produce CPD from coal is analyzed and feasibility is demonstrated according to theoretical calculations and reported results.This review provides a novel route for synthesis of HED fuels from coal.

关 键 词：High-energy-density Fuel ALKANE PETROLEUM CYCLOPENTADIENE Coal 

分 类 号：TQ517[化学工程]