复合载体Nb_(2)O_(5)-γ-Al_(2)O_(3)对Ni-B非晶态合金催化剂加氢脱硫性能的影响  

Effect of Composite Support Nb_(2)O_(5)-γ-Al_(2)O_(3) and Mo Doping on Hydrodesulfurization Performance of Ni-B Amorphous Alloy Catalyst

作　　者：亓雪 谌伟庆[2] 张世翔 张宜凡 潘洪志[1] Qi Xue;Chen Weiqing;Zhang Shixiang;Zhang Yifan;Pan Hongzhi(Shanghai University of Medical and Health Sciences,Shanghai 201318,China;College of Materials Science and Engineering,Nanchang University,Nanchang 330031,China)

机构地区：[1]上海健康医学院,上海201318 [2]南昌大学材料科学与工程学院,江西南昌330031

出　　处：《山东化工》2021年第17期28-29,32,共3页Shandong Chemical Industry

摘　　要：采用酸性的Nb_(2)O_(5)和高比表面的γ-Al_(2)O_(3)制备了复合载体Nb_(2)O_(5)-γ-Al_(2)O_(3),并负载Ni-B非晶态合金得到负载型催化剂。通过对催化剂的酸性及酸强度测定,考察了复合载体对催化活性的影响。结果表明,当载体中Nb_(2)O_(5)含量为30%时,因适量B酸和L酸的协同作用使得催化剂的活性最高,达到78.4%。Composite support Nb_(2)O_(5)-γ-Al_(2)O_(3) was prepared using acidic Nb_(2)O_(5) andγ-Al_(2)O_(3) with high specific surface,and then supported catalysts were obtained by loading Ni-B amorphous alloy.The effect of the composite support on the catalytic activity was investigated by measuring the acidity and acid strength of the catalyst.When the content of Nb_(2)O_(5) in the support is 30%,the synergistic effect of proper amount of B acid and L acid made the catalyst have the highest activity,reaching 78.4%.

关 键 词：非晶态合金 五氧化二铌 镍 硼 噻吩 加氢脱硫 

分 类 号：O643[理学—物理化学]