Synthesis of benzo[b]phosphole-based alkynylgold(I)complexes with resistive memory properties modulated by donor–acceptor chromophores  

作　　者：Yat-Hin Cheng Eugene Yau-Hin Hong Ming-Yi Leung Shiu-Lun Lai Vivian Wing-Wah Yam 

机构地区：[1]Institute of Molecular Functional Materials and Department of Chemistry,The University of Hong Kong,Hong Kong,China

出　　处：《SmartMat》2021年第3期406-418,共13页智能材料（英文）

摘　　要：A class of benzo[b]phosphole-based alkynylgold(I)complexes has been synthesized and characterized.These complexes share a similar benzo-[b]phosphole ligand,in which the phosphole moiety is substituted with variousπ-conjugated units with different donor strengths,namely phenoxazinylphenyl,tris(di-tert-butylcarbazolyl)phenyl and 2,4-dimethylphenyl moieties.These phosphole-containing gold(I)complexes are found to be strongly luminescent in toluene with tunable emission maxima and possess solvatochromic behaviors,suggesting an emission of metal-perturbed intraligand charge transfer origin.Cyclic voltammetry studies reveal that the presence of gold(I)metal center strongly perturbs the electronic properties of the phosphole moiety of the resultant complexes,which can be further finetuned by the auxiliary ligand on the gold(I)center.In the resistive memory studies,devices based on these alkynylgold(I)complexes exhibit satisfactory binary memory behaviors,demonstrating low threshold voltages in narrow distributions,high durability and low misreading rates.Such performances are believed to be originated from a field-induced charge transfer of the alkynylgold(I)complexes,in which the electron-accepting phosphole-gold(I)unit plays a crucial role in stabilizing the charge transfer state and that led to the observed resistive switching and memory behavior.

关 键 词：alkynylgold(I)complexes benzo[b]phosphole charge transfer DONOR-ACCEPTOR resistive memories 

分 类 号：O62[理学—有机化学]