聚磷腈的合成及应用研究进展  

Research progress on synthesis and application of polyphosphazene

作　　者：张晓光 毛明珍[2,3] 黎汉生[1] 王伯周 ZHANG Xiao-guang;MAO Ming-zhen;LI Han-sheng;WANG Bo-zhou(School of Chemistry and Chemical Engineering,Beijing Institute of Technology,Beijing 100081,China;Xi’an Modern Chemistry Research Institute,Xi’an 710065,China;State Key Laboratory of Fluorine&Nitrogen Chemicals,Xi’an 710065,China)

机构地区：[1]北京理工大学化学与化工学院,北京100081 [2]西安近代化学研究所,陕西西安710065 [3]氟氮化工资源高效开发与利用国家重点实验室,陕西西安710065

出　　处：《应用化工》2021年第9期2484-2489,共6页Applied Chemical Industry

基　　金：国家自然科学基金(21975199)。

摘　　要：介绍了聚磷腈及中间体聚二氯磷腈的制备方法:聚磷腈由聚二氯磷腈和亲核取代试剂发生亲核反应制备;聚二氯磷腈由热开环和活性阳离子两种聚合法制备,热开环法又分为溶剂聚合、原位聚合和三氯化磷法。溶剂热开环聚合法由于获得的聚合物分子量分布较窄、分子量大和工艺条件温和等优点,适合于工业化制备。较全面地总结了聚磷腈在阻燃材料、生物医用材料、导电材料、膜材料等领域近期的研究进展和发展趋势。The preparation methods of polyphosphazene and poly(dichlorophosphazene)were introduced.Using poly(dichlorophosphazene)and nucleophilic reagents(sodium alkoxides,aryloxides or amines)as the starting materials,poly(dichlorophosphazene)was prepared by the nucleophilic subsititution reaction.Poly(dichlorophosphazene)is prepared by two polymerization methods including thermal-open ring polymerization and active cation polymerization.Thermal-open ring polymerization is divided into solvent polymerization,in-situ polymerization and phosphorus trichloride polymerization.Solvent thermal open-loop polymerization is suitable for industrial preparation due to its advantages such as narrow molecular weight distribution,large molecular weight and mild technological conditions.The research progress of polyphosphazene in the fields of flame retardant materials,biomedical materials,conductive materials,membrane materials were reviewed.

关 键 词：聚磷腈 合成 应用 研究进展 

分 类 号：TQ333.99[化学工程—橡胶工业]