一种三唑类配合物对高氯酸铵的催化性能研究  

Catalytic decomposition of ammonium perchlorate base ona triazole energetic complex

作　　者：冯海萌 赵向华 罗小凡 马永娟 麻晓霞[1,2] FENG Haimeng;ZHAO Xianghua;LUO Xiaofan;MA Yongjuan;MA Xiaoxia(Department of Chemistry&Chemical Engineering,Ningxia University,Yinchuan Ningxia 750021,China;State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering,Yinchuan Ningxia 750021,China)

机构地区：[1]宁夏大学化学化工学院,宁夏银川750021 [2]省部共建煤炭高效利用与绿色化工国家重点实验室,宁夏银川750021

出　　处：《石油化工应用》2021年第9期113-116,共4页Petrochemical Industry Application

摘　　要：以3-氨基-1,2,4-三唑-5-羧酸(Hatzc)为配体,通过水热法合成了一种新型含能配合物Ce(atzc)2(H2O),利用红外光谱法、热重分析法、紫外光谱法、元素分析等手段对其结构进行了表征。通过差示扫描量热仪(DSC)研究其对高氯酸铵(AP)的催化热分解,表明其对高氯酸铵(AP)热分解有较好的催化活性,有应用于含能燃烧催化剂的潜质。A novel energetic complex Ce(atzc)2(H2O)was synthesized by hydrothermal method with 3-amino-1,2,4-triazole-5-carboxylic acid(Hatzc)as ligand.Its structure was characterized by infrared spectroscopy,thermogravimetric analysis,ultraviolet spectroscopy and elemental analysis.In addition,the catalytic thermal decomposition of ammonium perchlorate(AP)with the title complex was investigated by differential scanning calorimetry(DSC),which showed that it has good catalytic activity for the thermal decomposition of ammonium perchlorate(AP).It has the potential to be applied to energetic material catalysts.

关 键 词：含能材料 3-氨基-1 2 4-三唑-5-羧酸 催化热分解 

分 类 号：O643.361[理学—物理化学]