A Zinc Based Coordination Polymer:Multi-functional Material for Humidity Sensor and Fluorescence Applications  被引量:2

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作  者:WANG Cheng-Peng KASHI Chiranjeevulu YE Xiao-Liang LI Wen-Hua WANG Guan-E XU Gang 王诚鹏;KASHI Chiranjeevulu;叶晓亮;李文华;王观娥;徐刚(College of Chemistry and Materials Science,Fujian Normal University,Fuzhou 350007,China;State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,China;University of Chinese Academy of Sciences,Beijing 100049,China;Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China,Fuzhou 350108,China;Key Laboratory of Jiangxi Province for Persistent Pollutants Control arid Resources Recycle(Nanchang Hangkong University),Nanchang 330063,China)

机构地区:[1]College of Chemistry and Materials Science,Fujian Normal University,Fuzhou 350007,China [2]State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,China [3]University of Chinese Academy of Sciences,Beijing 100049,China [4]Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China,Fuzhou 350108,China [5]Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle(Nanchang Hangkong University),Nanchang 330063,China

出  处:《Chinese Journal of Structural Chemistry》2021年第9期1138-1144,1108,共8页结构化学(英文)

基  金:the National Natural Science Foundation of China(21822109,2020000052,21905280,21975254,21950410532,24074283);Key Research Program of Frontier Science,CAS(QYZDB-SSW-SLH023);International Partnership Program of CAS(121835KYSB201800);the Natural Science Foundation of Fujian Province(2017J05094);China Post-doctoral Science Foundation(2019M662254);the Youth Innovation Promotion Association CAS(2018342);Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle Open Research Fund(ES202080085)。

摘  要:Coordination polymers with structurally designable and energy,fluorescence,electrical etc.properties,are expected to become the next generation of multifunctional materials.A new compound,Zn(OAc)SPhNH(HSPhNH_(2)=4-aminophenol),was hydrothermally synthesized using 4-aminophenol as template and balance anion.The single-crystal X-ray diffraction showed a two-dimensional(2 D)structure constructed of Zn(OAc)+and SPhNH-.This compound exhibited typical semiconductive behavior,whose conductivity increased with the raise of temperature.Moreover,the conductivity was positively correlated with humidity.The compound also showed blue light emission property,which indicates great potential applications in light-emitting diodes.

关 键 词:coordination polymer PHOTOLUMINESCENCE SEMICONDUCTOR humidity sensor CONDUCTIVITY 

分 类 号:TP212[自动化与计算机技术—检测技术与自动化装置] O641.4[自动化与计算机技术—控制科学与工程] TB34[理学—物理化学]

 

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