蒙脱土有机改性研究进展  被引量:14

Progress in Organic Modification of Montmorillonite

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作  者:黄志博 石艳[1] 吴晓辉[1] HUANG Zhi-bo;SHI Yan;WU Xiao-hui(State Key Laboratory of Organic-Inorganic Composites,Engineering Research Center of Elastomer Materials Energy Conservation and Resources,Key Laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials,Beijing University of Chemical Technology,Beijing 100029,China)

机构地区:[1]有机无机复合材料国家重点实验室,弹性体材料节能和资源化教育部工程研究中心,北京化工大学新型高分子材料制备与加工北京市重点实验室,北京化工大学材料科学与工程学院先进弹性体材料研究中心,北京100029

出  处:《高分子通报》2021年第10期1-10,共10页Polymer Bulletin

摘  要:蒙脱土(MMT)是一种储量巨大且廉价的天然矿物资源,具有独特的片层结构,是增强聚合物材料性能的一种高性价比填料。当MMT在聚合物基体中实现良好分散时,能够明显提高聚合物材料的力学性能、气密性能、热稳定性能和阻燃性能等。但因其表面的亲水性,导致与聚合物相容性差,难以实现良好分散,因此,必须对其进行有机化改性。本文从MMT的结构与改性机理出发,按不同的有机改性剂进行概述,高度凝练了近年来国内外对MMT有机改性方面的研究进展。Montmorillonite(MMT) is a natural mineral resource with huge reserves and low price. It has a unique lamellar structure and is a cost-effective filler to enhance the performance of polymer materials. When MMT is well dispersed in polymer matrix, it can obviously improve the mechanical properties, gas barrier properties, thermal stability and flame retardancy of polymer materials. However, it is difficult to get good dispersion in polymer matrix because the hydrophilicity of its surface leads to poor compatibility with polymers. Therefore, it must be organically modified. Based on the structure and modification mechanism of MMT, the types of organic modifier and research progress in organic modification MMT at home and abroad in recent years were summarized.

关 键 词:蒙脱土 有机改性 纳米复合材料 聚合物 

分 类 号:TQ314[化学工程—高聚物工业]

 

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