金属有机化合物的分析(Ⅵ)——极性与非极性二茂铁化合物的高效液相色谱研究  

Analysis of Organometallic Compounds (Ⅵ)——Reversed-Phase High Performance Liquid Chromatography of Polar and Nonpolar Ferrocene Compounds

作　　者：杨学谨[1] 孙月稳[1] 董襄朝[1] 师树简[2] 李逢泽[2] 曹世明[2] 张建国[2] Yang Xuejin;Sun Yuewen;Dong Xiangchao;Shi Shujian;Li Fengze;Cao Shiming;Chang Jianguo(Department of Chemistry,Nankai University,Tianjin;Department of Chemistry,University of Inner-Mongolia)

机构地区：[1]南开大学化学系 [2]内蒙古大学化学系

出　　处：《高等学校化学学报》1986年第6期513-518,共6页Chemical Journal of Chinese Universities

基　　金：中国科学院科学基金资助课题。

摘　　要：本文以国产YWG-C_(18)H_(3)_(7)(十八烷基键合微粒硅胶)为固定相,以不同比例的甲醇-水为流动相进行二茂铁化合物的反相高效液相色谱研究,分离了十一类共32种不同极性的二茂铁化合物,并探讨了它们在反相色谱中保留特性和分子结构的关系。In this paper, thirty-two ferrocene derivatives of different polarities have been separated by HPLC using ODS as stationary phase, methanol-water ( with different ratios ) as mobile phase, and the relations between the retention values in the reversed-phase HPLC and their molecular structures have been described.

关 键 词：金属有机化合物 高效液相色谱 二茂铁 反相色谱 保留特性 十八烷基键 分子结构 极性 

分 类 号：R28[医药卫生—中药学]