氢化铝锂新合成方法的研究  

A NEW ROUTE TO LITHIUM ALUMINIUN HYDRIDE(LiAlH4)

作　　者：申泮文[1] 张允什[1] 陈声昌[1] 袁华堂[1] 车荣睿[1] 班月霞 刘鼎容 Shen Pan wen;Zhang Yunshi;Chen Shengchang;Yuan Huatong;Che Rongrui;Ban Yuexia;Liu Dingrong(Nankai University,Tianjin)

机构地区：[1]南开大学 [2]天津医学院化学教研组

出　　处：《高等学校化学学报》1982年第2期169-172,共4页Chemical Journal of Chinese Universities

摘　　要：在略高溫度下,通过氯化锂和金属钠在氫气氛中的反应,得到了氢化锂和氯化钠的混合物。用通常的Schlesinger法将得到的混合物用于合成氢化铝锂。反应的副产物是氯化锂和氯化钠的混合物,可用不同方法将其分离,所得氯化锂用于再循环。A mixture(LiH+NaCl)of lithium hydride and sodium chloride was produced by the reaction of lithium chloride and metallic sodium in an atmosphere of hydrogen at slightly elevated temperature and used to synthesize lithium aluminium hydride by the usual Schlesinger method.The by-product of the reaction was a mixture of lithium chloride and sodium chloride,which was separated by various methods and the lithium chloride obtained was recycled.

关 键 词：氯化锂 金属钠 氢化铝锂 新合成方法 氢化锂 氯化钠 再循环 副产物 

分 类 号：TQ2[化学工程—有机化工]