Supramolecular Self-assembly of Amphiphilic Alkynylplatinum(II)2,6-Bis(N-alkylbenzimidazol-2′-yl)pyridine Complexes  

作　　者：Andy Shun-Hoi CHEUNG Sammual Yu-Lut LEUNG Franky Ka-Wah HAU Vivian Wing-Wah YAM 

机构地区：[1]Institute of Molecular Functional Materials and Department of Chemistry,The University of Hong Kong,Pokfulam Road,Hong Kong,P.R.China

出　　处：《Chemical Research in Chinese Universities》2021年第5期1079-1084,共6页高等学校化学研究（英文版）

基　　金：This work was supported by the Guangdong-Hong Kong-Macao Joint Laboratory of Optoelectronic and Magnetic Functional Materials(No.2019B121205002).

摘　　要：Alkynylplatinum(II)bzimpy complexes of trimethylammoniumbenzylethynyl ligand have been synthesized and characterized.Complexes with long alkyl chains have been found to exhibit interesting self-assembly properties in the acetonitrile solution.The amphiphilic nature of the complexes has led to the formation of nanorods,as revealed by electron microscopy experiments.Further increasing the polarity of the solvent media has given rise to the enhancement of low-energy emission.

关 键 词：solution. PLATINUM ALKYL 

分 类 号：O62[理学—有机化学]