Glaser Coupling of Substituted Anthracene Diynes on a Non-metallic Surface at the Vapor-Solid Interface  

作　　者：FENG Yuan HEYDARI Zahra LIU Chenghao ZHANG Nianyue CUCCIA Louis A. IVASENKO Oleksandr PEREPICHKA Dmitrii F. 

机构地区：[1]Jiangsu Key Laboratory for Carbon-Based Functional Materials&Devices,Institute of Functional Nano&Soft Materials(FUNSOM),Soochow University,Suzhou,215123,P.R.China [2]Department of Chemistry,McGill University,801 Sherbrooke Street West,Montreal,Québec,H3A 0B8,Canada [3]Division of Molecular Imaging and Photonics,Department of Chemistry,KU Leuven-University of Leuven,Celestijnenlaan 200F,B-3001,Leuven,Belgium [4]Department of Chemistry and Biochemistry,Concordia University,7141 Sherbrooke St.W.,Montreal,Québec,H4B 1R6,Canada

出　　处：《Chemical Research in Chinese Universities》2021年第5期1143-1148,共6页高等学校化学研究（英文版）

基　　金：This work was supported by the Natural Sciences and Engineering Research Council of Canada(NSERC)Discovery Grants,the National Natural Science Foundation of China(No.22102110);the Natural Science Foundation of Jiangsu Province,China(No.SBK2021040457);the NSERC Scholarship(No.PDF-532834-2019).

摘　　要：The direct polymerization via irreversible C-C coupling on inert substrates will give access to new low-dimensional advanced functional materials and simplify their industrial fabrication.In this work,we present our initial results in the application of Glaser coupling to the direct on-surface polymerization of a model diacetylene compound at the solid-vapor interface.The self-assembly of the monomer and polymerization products was characterized using scanning tunneling microscopy(STM).In addition,selected optical properties and the electronic structure of all compounds were investigated.

关 键 词：POLYMERIZATION COUPLING METALLIC 

分 类 号：O62[理学—有机化学]