Facile Access to Uranium and Thorium Phosphaethynolate Complexes Supported by Tren: Experimental and Theoretical Study  

作　　者：Jipan Yu Kang Liu Qunyan Wu Bin Li Xianghe Kong Kongqiu Hu Lei Mei Liyong Yuan Zhifang Chai Weiqun Shi 

机构地区：[1]Laboratory of Nuclear Energy Chemistry,Institute of High Energy Physics,Chinese Academy of Sciences,Beijing 100049,China [2]Engineering Laboratory of Advanced Energy Materials,Institute of Industrial Technology,Chinese Academy of Sciences,Ningbo,Zhejiang 315201,China

出　　处：《Chinese Journal of Chemistry》2021年第8期2125-2131,共7页中国化学（英文版）

基　　金：This work was supported by the National Science Fund for Distinguished Young Scholars(No.21925603);the National Natural Science Foundation of China(No.21806167);the Science Challenge Project(TZ2016004);the Youth Inn ovation Promoti on Association of CAS(2017020).

摘　　要：The issue of covale nee of acti nide complexes remai ns con troversial to date.The in troducti on of 2-phosphaethy nolate anion into acti・nide complexes is expected to in vestigate the reaction mode and the bon ding property.Herei n,we describe the function alizatio n of An(Tren^(TIPS))CI(1:An=U;2:An=Th)precursors with NaOCP(dioxane)_(2.5) through salt-elimination method leading to the formation of the corresponding uranium and thorium phosphaethynolate species:[U(Tren^(TIPS))(OCP)]⑶and[Th(Tren^(TIPS))(OCP)](4).

关 键 词：URANIUM THORIUM Tripodal ligand Computational chemistry Electronic structure 

分 类 号：O62[理学—有机化学]