聚α,α-二甲基-β-丙内酯与聚(1,2-丙二醇-丁二酸酯)ABA型嵌段共聚物的合成  

SYNTHESIS OF THE ABA TYPE BLOCK COPOLYMER OF POLYPIVALOLACTONE-POLY (1,2-PROPANDIOL ADIPIC ACID ESTER)-POLYPIVALOLACTONE

作　　者：黎书樨 蒋硕健[1] 冯新德[1] Li Shuxi;Jiang Shuojian;Feng Xinde(Department of Chemistry,Peking University,Beijing)

机构地区：[1]北京大学化学系 [2]纺织部科学院化纤中心

出　　处：《高等学校化学学报》1983年第6期782-788,共7页Chemical Journal of Chinese Universities

摘　　要：通过合成双羟端聚(1,2-丙二醇己二酸酯)(PPA),经丁二酸酐酰化得双羧端PPA,再经(Bu_(4)N)_(2)CO_(3)-THF铵化得铵化PPA,最后用铵化PPA与α,α-二甲基-β-丙内酯(PVL)嵌段共聚,首次合成了PPVL-PPA-PPVL的ABA型脂肪族聚酯嵌段共聚物。A new block copolymer of ABA type aliphatic polyester, polypiv-alolactone-poly (1 ,2-propandiol adipic acid ester) -polypivalolactone (PPVL-PPA-PPVL) was prepared through the synthesis of dihydroxy terminate PPA, dicarboxyl terminate PPA with succinic anhydride and then tetrabutyl ammonium salt of dicarboxyl terminate PPA by treating with (Bu4N)2CO3-THF and finally by the block copolymerization of tetrabutyl ammonium salt of dicarboxyl terminate PPA with PVL. The conversion of the block copolymerization of PVL was 93-96% and the efficiency of this polymerization was 95-96%,

关 键 词：嵌段共聚 己二酸酯 PPA 脂肪族聚酯 铵化 丁二酸酐 PPV THF 

分 类 号：TQ3[化学工程]