聚醚聚氨酯/环氧树脂互穿网络高聚物的研究(Ⅰ)  

The Investigation on Polyurethane and Epoxyresin Interpenetrating Polymer Networks

作　　者：赵彦群[1] 李玉玮[1] 王静媛[1] 汤心颐[1] 于旻[2] 杨毓华[2] Zhao Yaniun;Li Yuwei;Wang Jingyuan;Tang Xinyi;Yu Min;Yang Yuhua(Department of Chemistry,Jilin University,Changchun;Changchun Institute of Applied Chemistry,Chinese Acalemy of Sciences,Changchun)

机构地区：[1]吉林大学化学系 [2]长春应用化学研究所

出　　处：《高等学校化学学报》1988年第6期643-645,共3页Chemical Journal of Chinese Universities

基　　金：科学院基金。

摘　　要：互穿网络高聚物(IPN)是两种或多种交联聚合物的共混体。由于两种聚合物网络相互贯穿和缠结,链节间的永久锁结产生强迫互容,使不同聚合物达到最紧密混合,最大限度地控制多相体系的相分离,IPN材料显示不寻常的耐热,耐溶剂和高强度等特点,远远超过其聚合物本身的性能。在IPN中,两网络相互贯穿程度越高,相分离越低,这主要取决于构成聚合物本身的相容性和最终网络结合方式。In this paper, the synthesis of interpenetrating polymer nelworks(IPN) based on polyurethane and epoxide by simultaneous polymerization, the influence of various component on their morphology, gh-ss transition behavior,mechanical properties and thermostability are reported. The results show that PU/EP = 25/75exhibited the best, mechanical properties and thermostability due to the high degree of interpenetration among the networks. PU/Ep = 50/50 exhibited obvious phase separation and the poorest mechnical properties.

关 键 词：PU/EP 互穿网络 

分 类 号：TQ3[化学工程]