金属配合物催化CO_(2)转化为环碳酸酯的进展  

Research progress on conversion of CO_(2) to cyclic carbonates catalyzed by metal complexes

作　　者：王文珍[1] 赵赛迪 汪力 武晋娣 黄剑 刘泽旭 WANG Wenzhen;ZHAO Saidi;WANG Li;WU Jindi;HUANG Jian;LIU Zexu(College of Chemistry and Chemical Engineering,Xi'an Shiyou University,Xi'an 710065,Shaanxi,China;State Key Laboratory of Coordination Chemistry,Nanjing University,Nanjing 210093,Jiangsu,China)

机构地区：[1]西安石油大学化学化工学院,陕西西安710065 [2]南京大学配位化学国家重点实验室,江苏南京210093

出　　处：《精细化工》2021年第10期1956-1961,共6页Fine Chemicals

基　　金：陕西省自然科学基础研究计划(2020JQ-763,2019JQ-490,2019JZ-44);陕西省大学生创新创业训练计划(S202010705015);西安石油大学创新与实践能力培养计划(YCS20212106,YCS20212104)。

摘　　要：利用CO_(2)与环氧化合物的环加成反应制备环碳酸酯,具有100%的原子经济性、环境友好等特点,有利于缓解温室气体效应,有着重要的理论和现实意义。开发新颖、高效的催化体系是该反应顺利快速进行的关键所在。近年来,金属配合物催化体系在环氧化合物和CO_(2)环加成反应应用最多,催化效果最为出色。综述了金属配合物催化体系如主族金属、过渡金属、镧系金属以及3d-4f金属催化剂等在CO_(2)与环氧化物环加成反应领域的研究进展,为今后合成新型高效金属配合物催化体系提供重要参考。The cycloaddition reaction of CO_(2) and epoxy compounds to prepare cyclic carbonates acid has the characteristics of 100% atom economy and environmental friendliness, which is beneficial to alleviate the greenhouse effect and turn waste into treasure, and has important theoretical and practical significance.The development of novel and efficient catalytic system is the key to the smooth and rapid process of the reaction. In recent years, the catalytic system of metal complexes is most used in the cycloaddition reaction of epoxy compounds and CO_(2), and shows the best the catalytic effect. The research progress on catalytic systems of metal complexes such as main group metals, transition metals, lanthanide metals and 3 d-4 f metals in the cycloaddition reaction of CO_(2) and epoxy compounds is summarized. This review provides important reference for the synthesis of new and efficient catalyst systems of metal complexes in the future.

关 键 词：CO_(2) 温室气体 环碳酸酯 金属配合物 催化剂 

分 类 号：TQ13[化学工程—无机化工] O623.662[理学—有机化学]