一种二茂铁丙烯酮化合物对HS^(-)的识别  

Recognition of HS^(-)by a Ferrocene Propenone Compound

作　　者：钱月恩 吴亮 陈瑞琪 刘亚雯 Qian Yue’en;Wu Liang;Chen Ruiqi;Liu Yawen(School of Chemistry,Resources and Environment,Leshan Normal University,Leshan 614004,China)

机构地区：[1]乐山师范学院化学与资源环境学院,四川乐山614004

出　　处：《山东化工》2021年第19期147-148,共2页Shandong Chemical Industry

基　　金：乐山市科技局项目(20ZDYJ0271);大学生创新创业训练计划(S201910649096)。

摘　　要：以研磨法合成1-二茂铁-3-(2-呋喃基)丙烯酮,并利用荧光光谱法考察其在不同时间、浓度、pH值下,该丙烯酮对硫氢根离子的识别效果。得出在40 min识别反应到达平衡,浓度在8.3×10^(-4)mol/L时识别效果最佳,pH值为4时识别相应最高。1-Ferrocene-3-(2-furyl)propenone was synthesized by grinding method,and fluorescence spectroscopy was used to investigate its recognition effect on sulfhydryl ions under different time,concentration and pH.It is concluded that the recognition reaction reaches equilibrium at 40 minutes,the recognition effect is the best when the concentration is 8.3×10^(-4)mol/L,and the recognition response is the highest when the pH is 4.

关 键 词：二茂铁基丙烯酮 合成 荧光探针 

分 类 号：O625.43[理学—有机化学]