单分散聚合物微球的制备及功能化研究进展  

Research progress in preparation and functionalization of monodisperse polymer microspheres

作　　者：程增会[1] 张代晖 王基夫[1] 王春鹏[1] 储富祥[1] CHENG Zeng-hui;ZHANG Dai-hui;WANG Ji-fu;WANG Chun-peng;CHU Fu-xiang(Institute of Chemical Industry of Forest Products,CAF,National Engineering Laboratory for Biomass Chemical Utilization,Key and Open Laboratory of Forest Chemical Engineering,SFA,Key Laboratory of Biomass Energy and Material,Nanjing 210042,China)

机构地区：[1]中国林业科学研究院林产化学工业研究所,生物质化学利用国家工程实验室,国家林业局林产化学工程重点开放性实验室,江苏省生物质能源与材料重点实验室,江苏南京210042

出　　处：《应用化工》2021年第10期2822-2828,共7页Applied Chemical Industry

基　　金：国家自然科学基金(31971600);江苏省生物质能源与材料重点实验室基本科研业务费(JSBEM-S-202009)。

摘　　要：综述了单分散聚合物微球常用的制备方法(乳液聚合法、种子聚合法、分散聚合法、沉淀聚合法、悬浮聚合法和膜乳化法等),介绍了单分散聚合物微球的功能化研究进展,包括磁性微球、多孔微球、温度/pH响应微球、阳离子微球以及微球官能团化等等。最后提出了多种聚合方法的相互结合是制备功能性单分散聚合物微球的一大趋势,开发多功能的单分散聚合物微球、实现批量生产是其近期的重点研究方向。The commonly used synthetic methods of narrow or monodisperse polymer microspheres are reviewed,including precipitation polymerization,dispersion polymerization,emulsion polymerization,seed polymerization,and membrane emulsification,etc.Moreover,it also covers the functionalization of microspheres from the perspective of the preparation of magnetic microspheres,porous microspheres,temperature/pH-responsive microspheres,and cationic microspheres.The recent and future development direction of monodispersed microspheres is finally suggested,including the combination of multiple polymerization methods,the synthesis of multifunctional monodispersed microspheres and the realization of mass production.

关 键 词：聚合物微球 制备方法 功能化 单分散 聚合 

分 类 号：TQ311[化学工程—高聚物工业] O631[理学—高分子化学]