1,1′:4′,1′′:4′′,1′′′-四苯基-2,2′′′,4,4′′′-四甲酸锰配合物的合成及表征  

Synthesis and Characterization of 1,1′:4′,1′′:4′′,1′′′-Tetraphenyl-2,2′′′,4,4′′′-Manganese Tetraethic Acid Complexes

作　　者：薛韩[1] 何丹凤[1] 靳忠欣 武灵敏 XUE Han;HE Dan-feng;JIN Zhong-xin;WU Ling-min(Key Construction Laboratory of Oilf ield Applied Chemistry Province of Daqing Normal University,Daqing 163712,China)

机构地区：[1]大庆师范学院油田应用化学省高校重点建设实验室,黑龙江大庆163712

出　　处：《化工管理》2021年第31期67-69,97,共4页Chemical Engineering Management

基　　金：大庆师范学院博士科研启动基金(16ZR04);大庆师范学院国家培育基金项目(19ZR03);大庆师范学院校基金(14ZR18)。

摘　　要：文章实验采用水热合成的方法,探索出了一例新颖的锰氧配合物1,1′:4′,1′′:4′′,1′′′-四苯基-2,2′′′,4,4′′′-四甲酸二锰,之后采用单晶X射线衍射、元素分析、热重分析、粉末X线衍射等仪器对这种锰氧配合物进行了表征,结构分析表明化合物1由氧桥连的两个锰和六个1,1′:4′,1′′:4′′,1′′′-四苯基-2,2′′′,4,4′′′-四甲酸形成空间上的三维立体结构,在这个反应中多金属氧酸盐起到了催化作用。A novel manganese complex[Mn2O(1,1′:4′,1′′:4′′,1′′′-tetraphenyl-2,2′′′,4,4′′′-tetracarboxylic acid)H2O]·3H2O have been synthesized and studied by means of hydrothermal technique.The Manganese oxide complexes’crystal structures were characterized by elemental analysis,PXRD and single-crystal X-ray diffraction analysis.Bridging oxygen connecting the two manganese and six 1,1′:4′,1′′:4′′,1′′′-tetraphenyl-2,2′′′,4,4′′′-tetracarboxylic acid to form the three-dimensional structure.In this reaction polyoxometalates are the catalysts.

关 键 词：锰氧配合物 水热合成 晶体结构 多酸催化 

分 类 号：O621.25[理学—有机化学]