以醋酸乙烯酯为单体的再湿性水性胶粘剂的合成及性能研究  

Study on synthesis and properties of rewetting waterborne adhesivewith vinyl acetate as monomer

作　　者：邵霞 尹朋伟 付金昕 孙圆圆 朱加武 齐方正 Shao Xia;Yin Pengwei;Fu Jinxin;Sun Yuanyuan;Zhu Jiawu;Qi Fangzheng(School of Materials Science and Engineering,Shanghai Institute of Technology,Shanghai 201418,China)

机构地区：[1]上海应用技术大学材料科学与工程学院,上海201418

出　　处：《中国胶粘剂》2021年第10期1-4,19,共5页China Adhesives

基　　金：国家自然科学基金项目(U1332107);上海市建筑防水材料工程研究中心项目(18DZ2253200);上海市教委能力建设项目(J201212);上海应用技术大学复合材料重点学科建设项目(10210Q140001)。

摘　　要：以醋酸乙烯酯为主单体,采用丙烯酸和马来酸二丁酯改性,以过硫酸铵为引发剂、邻苯二甲酸二丁酯为增塑剂,制备具有再润湿性能的聚醋酸乙烯酯乳液,并对其外观、黏度、再湿性、固含量、玻璃化转变温度、红外光谱以及剥离强度进行测试和分析。研究结果表明:当m(醋酸乙烯酯)∶m(丙烯酸和马来酸二丁酯)=9∶1时,合成的再湿性胶粘剂的综合性能较优。Using vinyl acetate as the main monomer,modified with acrylic acid and dibutyl maleate,using ammonium persulfate as initiator and dibutyl phthalate as plasticizer,polyvinyl acetate emulsion with rewetting properties was prepared.And its appearance,viscosity,rewetting performance,solid content,glass transition temperature,infrared spectrum and peeling strength were tested and analyzed.The research results showed that when m(vinyl acetate)∶m(acrylic acid and dibutyl maleate)=9∶1,the comprehensive properties of the synthesized rewetting adhesive was excellent.

关 键 词：水性胶粘剂 再湿型 聚醋酸乙烯酯乳液 胶粘剂 

分 类 号：TQ433[化学工程]