火焰原子吸收光谱法测定变形高温合金GH4169中痕量钾、钠  

Determination of trace potassium and sodium in wrought superalloy GH4169 by flame atomic absorption spectrometry

作　　者：蒙益林 高帅 徐卉 丁优仙 姜海啸 高晋峰 Meng Yilin;Gao Shuai;Xu Hui;Ding Youxian;Jiang Haixiao;Gao Jinfeng(AECC Beijing Institute of Aeronautical Materials,Beijing Key Laboratory of Aeronautical Materials Testing and Evaluation,Key Laboratory of Science and Technology on Aeronautical Materials Testing and Evaluation,Aeroengine Corporation of China,Beijing 100095,China)

机构地区：[1]中国航发北京航空材料研究院,航空材料检测与评价北京重点实验室,中国航空发动机集团材料检测与评价重点实验室,北京100095

出　　处：《化学分析计量》2021年第11期50-54,共5页Chemical Analysis And Meterage

摘　　要：建立火焰原子吸收光谱法测定变形高温合金GH4169中痕量钾、钠。称取0.5000 g样品,用8 mL混合酸(硝酸-氢氟酸-水的体积比为1∶1∶1)溶解,加入5 mL丙酮以提升灵敏度,在选定的仪器工作条件下进行测定。结果表明,钾元素采用样品标准加入法,钠元素采用镍基体匹配标准曲线法,溶液中钾、钠的质量浓度在0~500μg/L范围内与吸光强度呈良好的线性关系,相关系数分别为0.9980、0.9983,钾、钠的检出限分别为0.000098%、0.000058%。钾、钠9次重复测定结果的相对标准偏差分别为2.8%~7.0%、2.2%~7.9%,加标回收率分别为97%~110%、95%~107%。该方法满足变形合金GH4169中钾、钠含量的检测要求。A method of determination of trace potassium and sodium in wrought Superalloy GH4169 by flame atomic absorption spectrometry were established.The sample was weighed at 0.5000 g and dissolved in 8 mL mixed acid(the volume ratio of nitric acid-hydrofluoric acid-water was 1∶1∶1),5 mL acetone was added to sample solution for increasing sensitivity.The determination was carried out under the working conditions of the selected instrument.The results showed that when potassium was adopted by sample standard addition calibration and sodium was adopted by matrix matched calibration,the mass concentration of potassium and sodium had good linear relationship with the spectral intensity in the range of 0-500μg/L,the correlation coefficients of potassium and sodium were 0.9980,0.9983,and the detection limits of potassium and sodium was 0.000098%、0.000058%,respectively.The relative standard deviations of determination results for potassium and sodium were 2.8%-7.0%and 2.2%-7.9%(n=9).The recovery for potassium and sodium were 97%-110%and 95%-107%.The method can meet the detection requirements of potassium and sodium in wrought superalloy GH4169.

关 键 词：变形高温合金GH4169 火焰原子吸收法 痕量元素 钾 钠 

分 类 号：O657.3[理学—分析化学]