芳香醇选择性催化氧化研究进展  

Advances in Selective Catalytic Oxidation of Aromatic Alcohols

作　　者：夏心铭 孙丹娜 王均瑶 王佳斌 蒋成君[1] XIA Xinming;SUN Danna;WANG Junyao;WANG Jiabin;JIANG Chengjun(School of Biological and Chemical Engineering,Zhejiang University of Science and Technology,Hangzhou 310023)

机构地区：[1]浙江科技学院生物与化学工程学院,杭州310023

出　　处：《化工生产与技术》2021年第5期15-23,I0002,共10页Chemical Production and Technology

摘　　要：叙述了近15年来芳香醇选择性催化氧化的研究进展,以金属催化剂为主要对象,阐述了金属催化剂的结构及其催化性能。选择性催化氧化芳香醇得到相应的醛是有机合成中获得芳香醛的重要合成方法之一。目前对芳香醇选择性催化氧化的研究主要集中在以分子氧或者双氧水作为氧化剂,寻找一种催化效果好且对环境友好的金属催化剂。扩大各个催化系统的范围,找到高催化氧化活性、高选择性、高转化率、高重复使用率、低成本、低毒性以及对环境友好的催化剂,开发更具有选择性的绿色催化氧化方法是未来研究的方向。The research progress of selective catalytic oxidation of aromatic alcohols in the past 15 years was described.The structure and catalytic performance of metal catalysts were expounded with metal catalysts as the main object.Selective catalytic oxidation of aromatic alcohols to corresponding aldehydes is one of the important synthesis methods for obtaining aromatic aldehydes in organic synthesis.At present,the research on selective catalytic oxidation of aromatic alcohols mainly focuses on using molecular oxygen or hydrogen peroxide as oxidant to find a metal catalyst with good catalytic effect and environmentally friendly.Expanding the scope of each catalytic system,finding catalysts with high catalytic oxidation activity,high selectivity,high conversion rate,high reuse rate,low cost,low toxicity and environmental friendliness,and developing green catalytic oxidation methods with more selectivity are the future research directions.

关 键 词：金属催化剂 氧化 芳香醇 芳香醛 绿色化学 

分 类 号：TQ224.1[化学工程—有机化工]