双咪唑盐银配合物[[(CH_(3)CH_(2)CH_(2)CH_(2){(CHNCHCHN)}CH_(2)]_(2)]^(2+)_(n)[(AgBr_(4))_(2)]_(n)^(2-)的合成与结构  

The Synthesis and Structure of Di-imidazolium Salt with Ag-Br Complex of[[(CH_(3)CH_(2)CH_(2)CH_(2){(CHNCHCHN)}CH_(2)]_(2)]^(2+)_(n)[(AgBr_(4))_(2)]_(n)^(2-)

作　　者：王志国[1] WANG Zhiguo(School of Chemistry and Chemical Engineering, Mianyang Teachers' Collge, Mianyang,Sichuan 621000)

机构地区：[1]绵阳师范学院化学与化学工程学院,四川绵阳621000

出　　处：《绵阳师范学院学报》2021年第11期1-6,共6页Journal of Mianyang Teachers＇ College

基　　金：四川省教育厅基金资助项目(13cz0016).

摘　　要：桥联咪唑盐[[(CH_(3)CH_(2)CH_(2)CH_(2){(CHNCHCHN)}CH_(2)]_(2)]^(2+)2Br^(-)与Ag_(2)O按照2∶1摩尔比在CH_(3)CN溶液中高温回流4 h,成功合成1,2-亚乙基-3,3’-丁基咪唑为阳离子的银-溴配合物[[(CH_(3)CH_(2)CH_(2)CH_(2){(CHNCHCHN)}CH_(2)]_(n)^(2+)[(AgBr_(4))_(2)]_(n)^(2-).配合物通过了元素分析,1HNMR和X-ray衍射表征表征.晶体结构表明晶体属于六方晶系,空间群为P63/m,化合物晶胞参数为a=16.0561(15),c=15.2490(13),V(A3)=3404.5(5)A3,Z=4,F(000)=1576,Dx=1.567 Mg m-3,μ=5.30 mm-1,R1=0.147,wR2=0.405.晶体结构表明,化合物是由阴阳离子构成,阳离子是亚乙基桥联双咪唑离子,阴离子是由Br离子和Ag离子通过Ag-Br键相互作用形成的聚合结构,银离子采取四面体的构型.The title complex[[(CH_(3)CH_(2)CH_(2)CH_(2){(CHNCHCHN)}CH_(2)]_(2)]^(2+)_(n)[(AgBr_(4))_(2)]_(n)^(2-)was synthesized by reaction of the bridged imidazolium[[(CH_(3)CH_(2)CH_(2)CH_(2){(CHNCHCHN)}CH_(2)]^(2+)2Br-with Ag_(2)O in a 2∶1 molar ratio at high temperature in CH_(3)CN The compound was characterized by elemental analysis,1H NMR and single-crystal X-ray diffraction.The crystal belongs to Hexagonal system with space group P63/m,with a=16.0561(15),c=15.2490(13),V(A3)=3404.5(5)A3,Z=4,F(000)=1576,Dx=1.567 Mg m-3,μ=5.30mm-1,R1=0.147,wR2=0.405.Crystal structure indications that the complex is composed of anions and Cation.The Cation is a methylene bridged di-imidazolium,the anion is a polymer interacted by Ag-Br bonds.The Ag atom adopts a tetrahedral structure.

关 键 词：银卡宾 丁基咪唑 合成 结构 

分 类 号：O622[理学—有机化学]