氢化柠檬基溴代物及叔胺的合成与结构分析  

Synthesis and structure analysis of hydrogenated limonyl bromide and tertiary amine

作　　者：彭云 昌家宇 肖转泉[2] 陈尚钘[1] 范国荣[1] 廖圣良[1] 王宗德[1] PENG Yun;CHANG Jia-yu;XIAO Zhuan-quan;CHEN Shang-xing;FAN Guo-rong;LIAO Sheng-liang;WANG Zong-de(College of Forestry,Jiangxi Agricultural University,East China Woody Fragrance and Flavor Engineering Research Center of National Forestry and Grassland Administration,Camphor Engineering Research Center of NFGA/Jiangxi Province, Nanchang 330045,China;College of Chemistry and Chemical Engineering,Jiangxi Normal University,Nanchang 330027,China)

机构地区：[1]江西农业大学林学院,国家林草局木本香料(华东工程技术研究中心),国家林草局/江西省樟树工程技术研究中心,江西南昌330045 [2]江西师范大学化学化工学院,江西南昌330027

出　　处：《化学研究与应用》2021年第11期2234-2239,共6页Chemical Research and Application

基　　金：国家重点研发计划课题项目(2017YFD0600704)资助;国家自然科学基金项目(31960295)资助;江西省主要学科学术与技术带头人培养计划项目(20204BCJL23045,20204BCJ22022)资助;江西省研究生创新专项资金项目(YC2020-S235)资助。

摘　　要：分别由香茅醇和四氢香叶醇进行溴化反应合成香茅基溴(1-溴-3,7-二甲基-6-辛烯)和四氢香叶基溴(1-溴-3,7-二甲基辛烷)。再以这两种溴代物为原料,分别与二甲胺、二乙胺、二正丙胺、吗啉反应合成得到8种氢化柠檬基叔胺。各化合物都用IR、^(1)H NMR、^(13)C NMR与MS分析方法表征了结构,并对叔胺的质谱分析数据进行了讨论。Citronelloyl bromide(1-bromo-3,7-dimethyl-6-octene)and tetrahydrogeraniyl bromide(1-bromo-3,7-dimethyl-octane)were synthesized by bromination reaction of citronellol and tetrahydrogeraniol,respectively.Then the two bromides were used as raw materials and reacted with dimethylamine,diethylamine,din-propylamine and morpholine respectively to synthesize 8 kinds of hydrogenated citronyl tert-amines.The structures of all compounds were characterized by IR,^(1)HNMR,^(13)CNMR and MS,and the results of mass spectrometry of tertiary amines were discussed.

关 键 词：香茅醇 四氢香叶醇 溴代 叔胺 结构分析 

分 类 号：O623.2[理学—有机化学]