State-of-the-art progress in the selective photo-oxidation of alcohols  

作　　者：Zewen Shen Yezi Hu Bingfeng Li Yingtong Zou Shaojun Li GWilma Busser Xiangke Wang Guixia Zhao Martin Muhler 

机构地区：[1]College of Environmental Science and Engineering,North China Electric Power University,Beijing 102206,China [2]Laboratory of Industrial Chemistry,Faculty of Chemistry and Biochemistry,Ruhr-Universität Bochum,Universitätsstrasse150,D-44780 Bochum,Germany

出　　处：《Journal of Energy Chemistry》2021年第11期338-350,I0007,共14页能源化学（英文版）

基　　金：This research was funded by the National Natural Science Foundation of China(21976054);the Fundamental Research Funds for the Central Universities(2020MS036);the Deutsche Forschungsgemeinschaft(DFG,German Research Foundation)within the collaborative research centre/transregio 247"Heterogeneous Oxidation Catalysis in the Liquid Phase,f.

摘　　要：Photocatalytic oxidation of alcohols has received more and more attention in recent years following the numerous studies on the degradation of pollutants, hydrogen evolution, and CO_(2) reduction by photocatalysis. Instead of the total oxidation of organics in the degradation process, the photo-oxidation of alcohols aims at the selective conversion of alcohols to produce carbonyl/acid compounds. Promising results have been achieved in designing the catalysts and reaction system, as well as in the mechanistic investigations in the past few years. This review summarizes the state-of-the-art progress in the photo-oxidation of alcohols, including the development of photocatalysts and cocatalysts, reaction conditions including the solvent and the atmosphere, and the exploration of mechanisms with scavengers experiment, electron paramagnetic resonance (EPR) and diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy. The challenges and outlook for the further research in this field are also discussed.

关 键 词：Alcohol oxidation PHOTOCATALYSIS Carbonyl compounds SELECTIVITY 

分 类 号：O643.36[理学—物理化学] O644.1[理学—化学]