Chiral Recognition and Resolution Based on Helical Polymers  

作　　者：Hui Zou Qi-Liang Wu Li Zhou Xiao-Hua Hou Na Liu Zong-Quan Wu 

机构地区：[1]Department of Polymer Science and Engineering,School of Chemistry and Chemical Engineering,Hefei University of Technology and Anhui Key Laboratory of Advanced Catalytic Materials and Reaction Engineering,Hefei 230009,China

出　　处：《Chinese Journal of Polymer Science》2021年第12期1521-1527,共7页高分子科学（英文版）

基　　金：by the National Natural Science Foundation of China(Nos.51803045,21971052,22071041 and 51673057);the Fundamental Research Funds for the Central Universities(No.JZ2021HGTB0084,PA2020GDSK0069 and PA2020GDSK0070).

摘　　要：Helical polymers have attracted a great deal of attention and been extensively investigated due to their various applications.One of the most importa nt applicati ons of helical polymers is chiral recog nition and resolutio n ofe nan tiomersforthe reas on that a pair of e nan tiomers is comm only with differe nt physiological and toxicological behaviors in biological systems.Helical polymers usually prese nt un expected high chiral recogniti on ability to a variety of racemic compo unds.Whatzs more,the chiral recog nition and resolution abilities of the system are depe ndent on the highly ordered helical structures of the helical polymers.This mini review mainly focuses on the recent progress in chiral recognition and resolution based on helical polymers.The synthetic methodology for helical polymers is firstly discussed briefly.Then recent advances of chiral recog nition and resoluti on systems based on helical polymers,especially polyacetylenes and polyisocya nides,are described.We hope this mini review will in spire more in terest in developing helical polymers and en courage further advances in chiral-related disciplines.

关 键 词：Helical polymer Chiral recog nition Chiral resolution POLYACETYLENES POLYISOCYANIDES 

分 类 号：O631.1[理学—高分子化学]