基于稀土离子荧光特性的智能温敏涂层研究现状  

Research Status of Intelligent Temperature Sensitive Coatings Based on Fluorescence Characteristics of Rare Earth Ions

作　　者：田浩亮 王浩[2] 金国[2] 张保森[3] 王长亮 郭孟秋 杜修忻 王天颖 张昂 肖晨兵 Tian Haoliang;Wang Hao;Jin Guo;Zhang Baosen;Wang Changliang;Guo Mengqiu;Du Xiuxin;Wang Tianying;Zhang Ang;Xiao Chenbing(Aviation Key Laboratory of Science and Technology on Advanced Corrosion and Protection for Aviation Material,AECC Beijing Institution of Aeronautical Materials,Beijing 100095,China;Institute of Surface Science and Technology,Harbin Engineering University,Harbin 150001,China;School of Materials Science and Engineering,Nanjing Institute of Technology,Nanjing 211167,China)

机构地区：[1]中国航发北京航空材料研究院航空材料先进腐蚀与防护航空科技重点实验室,北京100095 [2]哈尔滨工程大学表界面科学与技术研究所,黑龙江哈尔滨150001 [3]南京工程学院材料科学与工程学院,江苏南京211167

出　　处：《稀有金属材料与工程》2021年第10期3777-3785,共9页Rare Metal Materials and Engineering

基　　金：国家自然科学基金(52075508);北京市科技新星培养计划(Z191100001119040);国家科技重大专项(2017-VII-0012-0109)。

摘　　要：智能温敏涂层是一种新兴的功能性涂层,其具有实时检测温度变化的功能,可以在涂层使用过程中及时发现和及时处理温度的异常,减少了外部测温装置检测的误差以及测温时的不便利性。本文详细介绍了航空发动机温度检测的研究现状,并介绍了稀土荧光离子检测温度时所利用的上转换发光的原理。其测温优势在于实时检测,没有外接测温等方式对工件的形状尺寸要求,没有测温延迟。但不同稀土离子的测温温度段存在较大不同,无法兼顾所有的温度范围。还介绍了基于稀土荧光离子的温敏热障涂层的应用原理,该涂层在应用于航空发动机测温以及热障涂层性能检测等方面具有较大优势。总结了各国学者研究的不同的材料体系及其温度检测范围,分析了温敏热障涂层目前的应用现状以及未来发展趋势。Intelligent temperature sensitive coating is a new kind of functional coating,which has the function of real-time detection of temperature changes,can achieve the timely detection and treatment of abnormal temperature in the using process of coating.The measurement error of external temperature measuring device and the inconvenience of temperature measurement are reduced.In this paper,the research status of aeroengine temperature detection wasintroduced in detail,and the principle of upconversion luminescence used in rare earth ion temperature detection wasintroduced.The advantage oftemperature measurement lies in real-time detection,no requirements of external temperature measurement and other methods on the shape and size of the workpiece,no temperature measurement delay.However,the temperature measurement range of different rare earth ions is quite different,which can not take into account all the temperature ranges.The application principle of temperature sensitive thermal barrier coating(TBC)based on rare earth fluorescent ions wasalso introduced.The coating has great advantages in the application of aeroengine temperature measurement and TBC performance testing.This paper summarizedthe different material systems and their temperature detection range studied by scholars of various countries,and analyzedthe current application status and future development trend of temperature sensitive thermal barrier coatings.

关 键 词：温度检测 稀土离子 上转换发光 光学温度测量 温敏热障涂层 

分 类 号：TG174.4[金属学及工艺—金属表面处理]